I have another potential solution which is somewhat similar to yours. However, it is much easier to implement.
We know that oring wedging caused by its extrusion seems to be the root cause of the first shot being slower after extended period of a valve inactivity under high plenum pressures. So ultimatetly we want to avoid this situation:
My idea comes from the pneumatics world as well. There as so called back-up orings preventing from oring extrusion:
https://www.parker.com/Literature/O-Ring%20Division%20Literature/ORD%205700.pdf -> Back-up Rings – Section VI
I propose this approach:
The gap in the plug itself should be big enough to allow the rod to move freely. Its diameter can be about 0.05-0.08mm bigger than the rod itself. Next, a PTFE washer should be placed. It should be a tight fit over the rod and it should also be tight in relation to the external cylinder. The role of that PTFE washer is to be a backup oring. Next, we place some Dur90 oring - it can be the one suffering from stiction issues the least. We know that wedging will be eliminated with this approach. The rod will be guided by the PTFE washer, no longer rubbing the plug itself.
Sounds like a win win approach? Any weak points?