It is reasonable to assume that the limiting factor for pellet speeds in air guns is the speed of sound in the barrel. If you just let compressed air expand behind the pellet, then the pellet would only accelerate until its speed matches the speed of the expanding air, and the speed of the expanding air can't be faster than the speed of sound.
But, if you impart velocity onto the expanding air itself, then this might be able to compensate for this effect.
A bit like what they are doing in this video:
So, creating a nozzle behind the pellet might actually make it go faster, even if it would be a bit of a choke point. This could actually be quite easy to do on most air guns, by incorporating a choke into the probe (to create a nozzle with the barrel walls), assuming much less air resistance all the way through the port, valve and to the air tank (i.e. higher cross-sectional area).
like this:
View attachment 406778 (the second choke version is intended to be like the ports on some springers, which have stepped changes in diameter to induce eddies and reduce air resistance)