I couldn't find a link to the video of the special that you watched, but I found the "meat and potatoes". Here is the text:
"McLaren theorizes that the Titan failed not because it was made of carbon fiber, but because it was made of three dissimilar materials: carbon fiber, titanium, and Plexiglas for the porthole. "When you have different materials, different molecular structure, they have different coefficients of expansion and compression. And then you make repeated cycles in depth? Of course you're gonna work that seal loose. And that's why submarines don't run around with any portholes at all, come to think of it. It's a weak point.""
Here is a link to the article I found.
Since I originally posted this thread I have seen pictures of the interior of the Titan, and I must say that I am surprised that there aren't Titanium cross supports. Moving on.
This issue rings more true to me than the original theory about micro-cracks in the CF itself. My career is in analytical instrumentation, and a lot of these are running at over 1000C This causes big issues in thermal expansion coefficient of the different materials as the components heat up and cool down.
Again, this is a really interesting thread...based on the tragedy of a few explorers.